Reaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids.
نویسندگان
چکیده
The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a > b > c > d) to that observed for pristine C70 (α > β > γ > δ).
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 94 شماره
صفحات -
تاریخ انتشار 2015